METHODICAL ASPECTS OF THE CARBON DIOXIDE DETERMINING IN THE ATMOSPHERE BY USING of FTIR SPECTROSCOPY
Abstract
Monitoring the state of ground-based spectroscopic systems ensures high accuracy of atmospheric gas measurements and the possibility of using measurement data for validating satellite measurements and numerical models. Column-averaged carbon dioxide mixing ratios (XCO2) can be used to assess the quality of spectroscopic measurements because its content is stable in the atmosphere. We retrieved the XCO2 values from spectra measured by Fourier transform IR spectrometer Bruker 125HR (FTIR) between 2009 and 2017 at the Peterhof station (St. Petersburg, Russia). The total error of the FTIR CO2 columns retrieval is 4.18±0.02% with 0.36±0.06% and 4.16±0.02% for random and systematic errors, respectively. The data obtained are compared with model calculations based on long-term observations at the Mauna Loa station. Various schemes for the inverse problem solving are analyzed, their comparison is made among themselves, and estimates of empirical random errors in the determination of XCO2 are obtained. To improve the accuracy of XCO2 measurements, it is recommended simultaneously with the atmospheric gases measurements to determine the error of the Fourier-spectrometer phase and the slope of the zero line of the spectrum, taking into account various continuum sources of errors.
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Review
For citations:
Virolainen Ya.A. METHODICAL ASPECTS OF THE CARBON DIOXIDE DETERMINING IN THE ATMOSPHERE BY USING of FTIR SPECTROSCOPY. Zhurnal Prikladnoii Spektroskopii. 2018;85(3):453-460. (In Russ.)
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