CHEMICAL ELEMENT PROFILES IN COMMERCIAL WOVEN FABRIC COMBINING LASER-INDUCED BREAKDOWN SPECTROSCOPY AND CHEMOMETRICS
Abstract
High heterogeneity solid woven fabric samples were investigated using laser-induced breakdown spectroscopy (LIBS) and chemometrics. Many emission lines were relevant to characterize this material at the surface and in deeper layers of fibers. Differences among dyes and fibers were clearly observed. The scores maps showed the possibility of comparing the chemical compositions of the dye and fiber independent of the print of fabric. Variations in the composition were verified by carrying out a pattern for mapping using a sophisticated LIBS system. This screening can provide a fast evaluation of samples and may associate this information with classification, authenticity or even for forensic analysis of fabric materials.
About the Authors
M. . Cardoso Santos
Universidade Estadual Paulista (UNESP), Instituto de Química
Russian Federation
Russian Federation
C. . Dai
Universidade Estadual Paulista (UNESP), Instituto de Química
Russian Federation
Russian Federation
F. . Manhas Verbi Pereira
Universidade Estadual Paulista (UNESP), Instituto de Química
Russian Federation
Russian Federation
References
1. http://www.desenvolvimento.gov.br//sitio/interna/interna.php?area=5&menu=1161, accessed July, 2016.
2. J. Lademann, A. Patzelt, M. Worm, H. Richter, W. Sterry, M. Meinke, Laser Phys. Lett., 6, 759-763 (2009).
3. D. S. Brookstein, Dermatol. Clin., 27, 309-322 (2009).
4. I. Jäger, C. Hafner, K. Schneider, Mutat. Res., 561, 35-44 (2004).
5. C. J. Lord, A. Ashworth, Nature, 481, 287-294 (2012).
6. I. Rezic, I. Steffani, Microchem. J., 85, 46-51 (2007).
7. J. El Haddad, L. Canioni, B. Bousquet, Spectrochim. Acta B, 101, 171-182 (2014).
8. J. Kaiser, J. Novotný, M. Z. Martin, A. Hrdlička, R. Malina, M. Hartl, V. Adam, R. Kizek, Surf. Sci. Rep., 67, 233-243 (2012).
9. D. F. Andrade, E. R. Pereira-Filho, P. Konieczynski, J. Braz. Chem. Soc., DOI: 10.21577/0103-5053.20160236.
10. R. R. V. Carvalho, J. A. O. Coelho, J. M. Santos, F. W. B. Aquino, R. L. Carneiro, E. R. Pereira-Filho, Talanta, 134, 278-283 (2015).
11. E. A. Menezes, R. Carapelli, S. R. Bianchi, S. N. P. Souza, W. O. Matos, E. R. Pereira-Filho, A. R. A. Nogueira, J. Hazard. Mat., 182, 325-330 (2010).
12. ISO (International Organization for Standardization), ISO 3160/2 Watch Cases and Accessories; Gold Alloy Coverings. Part 2. Determination of Fineness, Thickness Corrosion Resistance and Adhesion, ISO, Geneva (2003).
13. 515-10 A. R. Horrocks, S. C. Anand, Handbook of Technical Textiles, CRC Press, Boca Raton (2000).
14. H. U. Jinlian, Structure and Mechanics of Woven Fabrics, John Wiley & Sons, Chichester (2000).
15. B. K. Sirkova, AUTEX Res. J., 12, 40-43 (2012).
16. C. C. I. Guaratini, M. V. B. Zanoni, Qui. Nova, 23, 71-78 (2000).
17. G. A. Galbács, Anal. Bioanal. Chem., 407, 7537-7562 (2015).
18. D. A. Cremers, L. J. Radziemski, Handbook of Laser-Induced Breakdown Spectroscopy, 2nd ed., John Wiley & Sons, Chichester (2013).
19. R. L. Carneiro, R. J. Poppi, Spectrochim. Acta, A, 118, 215-220 (2014).
20. N. N. Mahapatra, Textile Dyes, CRC Press, Boca Raton (2016).
Review
For citations:
Cardoso Santos M., Dai C., Manhas Verbi Pereira F. CHEMICAL ELEMENT PROFILES IN COMMERCIAL WOVEN FABRIC COMBINING LASER-INDUCED BREAKDOWN SPECTROSCOPY AND CHEMOMETRICS. Zhurnal Prikladnoii Spektroskopii. 2018;85(3):515(1)-515(10). (In Russ.)
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