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A METHOD OF THE TRANSPARENCY SPECTRA INVERSION FOR THE FREONES CONCENTRATION MEASUREMENT

Abstract

A technique is proposed for the selection of optimal parameters for solving the inverse problem of determining the total content (TC) of freons by ground-based spectrometric measurements of solar radiation. The technique is designed for measurements at the NDACC station “St. Petersburg” using a Fourier interferometer Bruker FS125HR. The proposed technique is implemented with reference to measurements of the total content of hydrochlorofluorocarbon R-22 (HCF2Cl). Based on the obtained optimal set of parameters, the retrieval of the R-22 TC over the St. Petersburg station was performed in the period 2009-2018. Estimates of measurement errors are obtained: the average systematic error is 4.8%, a random 3.7% for the entire observation period. Preliminary assessment of the trend was 2.64 ± 0.22% per year.

About the Authors

A. V. Polyakov
St. Petersburg State University
Russian Federation


Ya. A. Virolainen
St. Petersburg State University
Russian Federation


M. V. Makarova
St. Petersburg State University
Russian Federation


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Review

For citations:


Polyakov A.V., Virolainen Ya.A., Makarova M.V. A METHOD OF THE TRANSPARENCY SPECTRA INVERSION FOR THE FREONES CONCENTRATION MEASUREMENT. Zhurnal Prikladnoii Spektroskopii. 2018;85(6):962-970. (In Russ.)

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