OPTIMIZATION OF DETERMINING CHLORINE NITRATE IN THE ATMOSPHERE FROM GROUND-BASED SPECTROSCOPIC MEASUREMENTS
Abstract
The methodological aspects of determining the total content of chlorine nitrate (ClONO2) from groundbased measurements of solar radiation spectra using a Bruker 125HR Fourier spectrometer at the St. Petersburg station (59.88° N, 29.82° E, 20 m above sea level) of the international observational network NDACC are considered. The developed technique was applied to the spectra measured in the period from 2009 to 2019, and the results were compared with the calculations by the EMAC chemistry-climate model. A good qualitative and quantitative agreement of the experimental data with the results of numerical modeling was obtained. For the period 2009—2017, the average mismatch between the model and experimental ensembles was 3%, the standard deviation was 43%, and the correlation coefficient was 0.79 ± 0.02, which indicates an adequate description of the variability of the total ClONO2 content by the model. The assessment of the linear trend of the total ClONO2 content showed a significant decrease in the total chlorine nitrate content in the atmosphere over St. Petersburg both according to ground-based measurements (–2.3 ± 1.9% per year) and modeling results (–1.2 ± 0.4% per year).
About the Authors
Y. A. Virolainen
St. Petersburg State University
Russian Federation
St. Petersburg
Russian Federation
St. Petersburg
A. V. Polyakov
St. Petersburg State University
Russian Federation
St. Petersburg
Russian Federation
St. Petersburg
O. Kirner
Karlsruhe Institute of Technology, Steinbuch Centre for Computing
Germany
Eggenstein-Leopoldshafen, 76344
Germany
Eggenstein-Leopoldshafen, 76344
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Review
For citations:
Virolainen Y.A., Polyakov A.V., Kirner O. OPTIMIZATION OF DETERMINING CHLORINE NITRATE IN THE ATMOSPHERE FROM GROUND-BASED SPECTROSCOPIC MEASUREMENTS. Zhurnal Prikladnoii Spektroskopii. 2020;87(2):306-313. (In Russ.)
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