SPECTRAL-LUMINESCENT PROPERTIES AND NH-TAUTOMERISM OF FREE BASES OF THE CORROLE ALKYLATED DERIVATIVES

Y. H. Ajeeb; D. V. Klenitsky; I. V. Vershilovskaya; D. V. Petrova; A. S. Semeikin; W. Maes; L. L. Gladkov; M. M. Kruk

SPECTRAL-LUMINESCENT PROPERTIES AND NH-TAUTOMERISM OF FREE BASES OF THE CORROLE ALKYLATED DERIVATIVES

Y. H. Ajeeb, D. V. Klenitsky, I. V. Vershilovskaya, D. V. Petrova, A. S. Semeikin, W. Maes, L. L. Gladkov, M. M. Kruk

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Abstract

The molecular structure and spectral-luminescent properties of free bases of 2,3,7,13,17,18- hexamethyl-8,12-di-n-butylcorrole and 7,13-dimethyl-8,12-di-n-butylcorrole in solutions in the temperature range of 288—328 K were studied by methods of luminescent and absorption spectroscopy and quantum chemistry. Absorption and fluorescence spectra of studied compounds were shown to be the superimposed spectra of two NH-tautomers. Individual tautomer spectra were identified and bands were assigned to specific transitions. NH-tautomer equilibriums in the ground S0 and lower excited S1 singlet states were characterized.

Keywords

corrole free bases, NH-tautomerism, spectra, fluorescence, molecular conformation

References

1. A. W. Johnson, I. T. Kay. J. Chem. Soc. (1965) 1620-1629

2. Z. Gross, N. Galili, I. Saltsman. Angew. Chem., Int. Ed., 38 (1999) 1427-1429

3. R. Paolesse, L. Jaquinod, D. Nurco, S. Mini, F. Sagone, T. Boschi, K. M. Smith. Chem. Commun., (1999) 1307-1308

4. Yu. B. Ivanova, V. A. Savva, N. Zh. Mamardashvili, A. S. Starukhin, T. H. Ngo, W. Dehaen, W. Maes, M. M. Kruk. J. Phys. Chem. A, 116 (2012) 10683-10694

5. M. M. Kruk, T. H. Ngo, P. Verstappen, A.S. Starukhin, J. Hofkens, W. Dehaen, W. Maes. J. Phys. Chem. A, 116 (2012) 10695-10703

6. M. M. Kruk, T. H. Ngo, V. A. Savva, A. S. Starukhin, W. Dehaen, W. Maes. J. Phys. Chem. A, 116 (2012) 10704-10711

7. W. J. D. Beenken, M. Presselt, T. H. Ngo, W. Dehaen, W. Maes, M. M. Kruk. J. Phys. Chem. A, 118 (2014) 862-871

8. V. N. Knuykshto, T. H. Ngo, W. Dehaen, W. Maes, M. M. Kruk. RSC Adv., 6 (2016) 43911-43915

9. M. M. Kruk, D. V. Klenitsky, W. Maes. Macroheterocycles, 12 (2019) 58-67

10. M. M. Kruk, D. V. Klenitsky, L. L. Gladkov, W. Maes. J. Porph. Phthal., 23 (2020) 1-10

11. T. Ding, E. A. Aleman, D. A. Modarelli, C. J. Ziegler. J. Phys. Chem. A, 109 (2005) 7411-7417

12. B. Ventura, A. D. Esposti, B. Koszarna, D. T. Gryko, L. Flamigni. New. J. Chem., 29 (2005) 1559-1566

13. T. Ding, J. D. Harvey, C. J. Ziegler. J. Porph. Phthal., 9 (2005) 22-27

14. D. B. Berezin, D. R. Karimov, A. V. Kustov. Korroly i ikh proizvodnye: sintez, svoistva, perspektivy prakticheskogo primeneniya, Moskva, LENAND (2018)

15. D. B. Berezin, D. R. Karimov, A. S. Semeikin, B. D. Berezin. Kord. khimiya, 33 (2007) 871-878

16. D. R. Karimov, V. P. Barannikov, O. V. Mal'tseva, R. S. Kumeev, D. B. Berezin. Izv. vuzov, Ser. khim. i khim. tekhnol., 54 (2011) 26-33

17. C. M. Lemon, R. L. Halbach, M. Huynh, D. G. Nocera. Inorg. Chem., 54 (2015) 2713-2725

18. M. Gouterman. In: The Porphyrins, Ed. D. Dolphin, Vol. 3, New York (1978) 1-165

19. M. M. Kruk, A. S. Starukhin, W. Maes. Macroheterocycles, 4 (2011) 69-79

20. C. J. Ziegler, J. R. Sabin, R. Geier III, V. N. Nemykin. Chem. Commun., 48 (2012) 4743-4745

21. Yu. Kh. Adzhib, T. B. Karlovich, L. L. Gladkov, V. Maes, N. N. Kruk. Zhurn. prikl. spektr., 86 (2019) 345-351 [Y. H. Ajeeb, T. B. Karlovich, L. L. Gladkov, W. Maes, M. M. Kruk. J. Appl. Spectr., 86 (2019) 389-395]

22. N. N. Kruk, D. V. Klenitskii, V. Maes. Tr. BGTU. Ser. 3. Fiz.-mat. nauki i inform., 206 (2018) 36-42

23. N. N. Kruk, D. V. Klenitskii, L. L. Gladkov, V. Maes. Tr. BGTU. Ser. 3. Fiz.-mat. nauki i inform., 218 (2019) 20-26

24. N. N. Kruk, D. V. Klenitskii, V. Maes. Tr. BGTU. Ser. 3. Fiz.-mat. nauki i inform., 230 (2020) 32-37

25. D. V. Petrova, A. S. Semeikin, N. M. Berezina, M. B. Berezin, M. I. Bazanov. Macroheterocycles, 12 (2019) 119-128

26. J. N. Demas, G. A. Crosby. J. Phys. Chem., 75 (1971) 991-1024

27. I. V. Vershilovskaya, S. Stefani, P. Verstappen, T. H. Ngo, I. G. Scheblykin, W. Dehaen, W. Maes, M.M. Kruk. Macroheterocycles, 10 (2017) 257-267

28. D. N. Laikov. Chem. Phys. Lett., 281 (1997) 151-156

29. D. N. Laikov, Yu. A. Ustynyuk. Rus. Chem. Bull., 54 (2005) 820-826

30. J. Waluk. In: Handbook of Porphyrin Science, Eds. K. M. Kadish, K. M. Smith, R. Guillard, Vol. 7, New York (2010) 359-438

31. S. L. Murov, I. Carmichael, G. L. Hug. Handbook of Photochemistry, New York (1993)

32. M. O. Senge. In: The Porphyrin handbook, Eds. K. M. Kadish, K. M. Smith, R. Guillard, Vol. 1, New York (2000) 239-347

33. M. O. Senge, S. A. MacGovan, J. O’Brien. Chem. Commun., 51 (2015) 17031-17063

For citations:

Ajeeb Y.H., Klenitsky D.V., Vershilovskaya I.V., Petrova D.V., Semeikin A.S., Maes W., Gladkov L., Kruk M.M. SPECTRAL-LUMINESCENT PROPERTIES AND NH-TAUTOMERISM OF FREE BASES OF THE CORROLE ALKYLATED DERIVATIVES. Zhurnal Prikladnoii Spektroskopii. 2020;87(3):378-386. (In Russ.)

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Zhurnal Prikladnoii Spektroskopii

SPECTRAL-LUMINESCENT PROPERTIES AND NH-TAUTOMERISM OF FREE BASES OF THE CORROLE ALKYLATED DERIVATIVES

Full Text:

Abstract

Keywords

About the Authors

References

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Zhurnal Prikladnoii Spektroskopii

SPECTRAL-LUMINESCENT PROPERTIES AND NH-TAUTOMERISM OF FREE BASES OF THE CORROLE ALKYLATED DERIVATIVES

Full Text:

Abstract

Keywords

About the Authors

References

Review

For citations:

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