STRUCTURE AND LUMINESCENCE PROPERTIES OF LUTETIUM(III)-COMPLEXES WITH 5,10,15,20-TETRAPHENYLPORPHIN AND ITS DERIVATIVES
Abstract
The spectral-luminescent properties of new complexes of chloro-lutetium(III) with 5,10,15,20-tetra- phenylporphin and its mono-nitrophenyl derivative having a para-nitro group in one of the meso-phenyl rings were studied. The studied complexes show weak fluorescence (φfl = 5 ⋅ 10–4) and moderate phospho- rescence (φphosph = 3 ⋅ 10–2) and also phosphorescence at room temperature at 77 K. The type of an extra ligand (monodentate — chlorine and bidentate — acetylacetonate) as well as the presence of electron- withdrawing NO2 group in the meso-phenyl ring have no appreciable effect on photophysics of Lu(III) por- phyrins. The phosphorescence spectrum of the studied complexes is shifted to the long-wavelength region, and the phosphorescence lifetimes are longer (2800–3100 µs) than those of the known oxygen sensors — Pt(II)- or Pd(II)-porphyrins. The value of the oxygen determination limit in solutions was estimated from the quenching of the phosphorescence of the studied Lu(III) porphyrins.
About the Authors
M. P. Tsvirko
Jan Długosz University in Czestochowa
Poland
Czestochowa, 42-200, Poland
Poland
Czestochowa, 42-200, Poland
B. Kalota
Jan Długosz University in Czestochowa
Poland
Czestochowa, 42-200, Poland
Poland
Czestochowa, 42-200, Poland
A. Mikus
Warsaw University of Technology
Poland
Warsaw, 00-664, Poland
Poland
Warsaw, 00-664, Poland
S. Ostrowski
Warsaw University of Technology
Poland
Warsaw, 00-664, Poland
Poland
Warsaw, 00-664, Poland
References
1. V. Bulach, F. Sguerra, M. W. Hosseini. Coord. Chem. Rev., 256 (2012) 1468—1478
2. H. He. Coord. Chem. Rev., 273-274 (2014) 87—99
3. A. F. Mironov. Russ. Chem. Rev., 82 (2013) 333—351
4. T. J. Foley, B. S. Harrison, A. S. Knefely, K. A. Abboud, J. R. Reynolds, K. S. Schanze, J. M. Boncella. Inorg. Chem., 42 (2003) 5023—5032
5. Т. Ф. Качура, А. Н. Севченко, К. Н. Соловьев, М. П. Цвирко. Докл. АН СССР, 217 (1974) 1121—1134 [T. F. Kachura, A. N. Sevchenko, K. N. Solovyov, M. P. Tsvirko. Dokl. Phys. Chem., 217 (1974) 783—786]
6. B. S. Harrison, T. J. Foley, M. Bouguettaya, J. M. Boncella, J. R. Reynolds, K. S. Schanze, J. Shim, P. H. Holloway, G. Padmanaban, S. Ramakrishnan. Appl. Phys. Lett., 79 (2001) 3770—3772
7. В. Е. Пятосин, М. П. Цвирко. Опт. и спектр., 70 (1991) 379—383
8. B. Kalota, M. Tsvirko. Chem. Phys. Lett., 634 (2015) 188—193
9. L. A. Martarano, C.-P. Wong, W. D. Horrocks Jr., A. M. Ponte Goncalves. J. Phys. Chem., 80 (1976) 2389—2393
10. S. A. Vinogradov, D. F. Wilson. J. Chem. Soc., Perkin Trans., 2 (1995) 103—111
11. С. С. Дворников, К. Н. Соловьев, М. П. Цвирко. Биофизика, 24 (1979) 791—796
12. K. Koren, S. M. Borisov, R. Saf, I. Klimant. Eur. J. Inorg. Chem. (2011) 1531—1534
13. V. S. Chirvony, A. van Hoek, T. J. Schaafsma, P. P. Pershukevich, I. V. Filatov, I. V. Avilov, S. I. Shishporenok, S. N. Terekhov, V. L. Malinovskii. J. Phys. Chem. B, 102 (1998) 9714—9724
14. V. Knyukshto, E. Zenkevich, E. Sagun, A. Shulga, S. Bachilo. Chem. Phys. Lett., 304 (1999) 155—166
15. C. Farley, A. Aggarwal, S. Singh, A. Dolor, P. To, A. Falber, M. Crossley, C. M. Drain. J. Comput. Chem., 39 (2018) 1129—1142
16. Н. В. Ивашин, С. Н. Терехов. Опт. и спектр., 126 (2019) 285—294
17. B. Kalota, A. Mikus, S. Ostrowski. New J. Chem., 40 (2016) 9899—9902
18. В. Н. Кнюкшто, А. С. Старухин, М. М. Крук, А. В. Горский. Журн. прикл. спектр., 84, No 6 (2017) 877—883 [V. N. Knyukshto, A. S. Starukhin, M. M. Kruk, A. V. Gorskii. J. Appl. Spectr., 84 (2017) 960—965]
19. G. Baryshnikov, B. Minaev, H. Ågren. Chem. Rev., 117 (2017) 6500—6537
20. M. Gouterman, L. K. Hanson, G. E. Khalil, J. W. Buchler, K. Rohbock, D. Dolphin. J. Am. Chem. Soc., 97 (1975) 3142—3149
21. А. Т. Градюшко, М. П. Цвирко. Опт. и спектр., 31 (1971) 548—556
22. В. Е. Пятосин, М. П. Цвирко, К. Н. Соловьев, Т. Ф. Качура. Опт. и спектр., 52 (1982) 269—275
23. J. Aaviksoo, A. Freiberg, S. Savikhin, G. F. Stelmakh, M. P. Tsvirko. Chem. Phys. Lett., 111 (1984) 275—278
24. D. Eastwood, M. Gouterman. J. Mol. Spectr., 35 (1970) 359—375
25. S. Faure, C. Stern, R. Guilard, P. D. Harvey. Inorg. Chem., 44 (2005) 9232—9241
26. R. D. Shannon. Acta Cryst., A32 (1976) 751—767
Review
For citations:
Tsvirko M.P., Kalota B., Mikus A., Ostrowski S. STRUCTURE AND LUMINESCENCE PROPERTIES OF LUTETIUM(III)-COMPLEXES WITH 5,10,15,20-TETRAPHENYLPORPHIN AND ITS DERIVATIVES. Zhurnal Prikladnoii Spektroskopii. 2020;87(5):706-713. (In Russ.)
Views: 292
Email this article 