DETECTION OF ETHYLENEDIAMINE VAPOR BY OPTICAL WAVEGUIDE SENSOR BASED ON TETRAKIS-CARBOXYLPHENYL PORPHYRIN FILM
Abstract
A sensitive element was prepared by the spin coating method on the surface of a K+ exchange glass optical waveguide by dissolving tetrakis-carboxyphenyl porphyrin (TCPP) in the nontoxic solvent ethanol. The TCPP sensitive element detected 18 volatile organic compounds with an excellent selective response to ethylenediamine (EDA) gas. On this basis, the effects of the solvent, solution mass fraction, speed of the homogenizer and atmospheric humidity on the detection of EDA gas by the sensitive element were discussed. The formation of hydrogen bonds between TCPP and EDA molecules is proposed, which leads to changes in the morphology and light absorbance of the sensing film.
Keywords
tetrakis-carboxylphenyl porphyrin,
optical waveguide sensor,
volatile organic compounds,
ethylenediamine
Supporting agencies: This work was supported by the National Natural Science Foundation of China (Grant No. 21765021). We thank Liwen Bianji, Edanz Group China (www.liwenbianji.cn/ac) for editing the English text of a draft of this manuscript.
About the Authors
Qingrong Ma
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Yuan Zhang
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Hannikezi Abudukeremu
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Asiya Maimaiti
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Kediliya Wumaier
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Patima Nizamidin
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
Abliz Yimit
College of Chemistry and Chemical Engineering, Xinjiang University
China
Urumqi 830046
China
Urumqi 830046
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Review
For citations:
Ma Q., Zhang Yu., Abudukeremu H., Maimaiti A., Wumaier K., Nizamidin P., Yimit A. DETECTION OF ETHYLENEDIAMINE VAPOR BY OPTICAL WAVEGUIDE SENSOR BASED ON TETRAKIS-CARBOXYLPHENYL PORPHYRIN FILM. Zhurnal Prikladnoii Spektroskopii. 2020;87(5):856(1)-856(8).
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