FORMATION OF SUPRAMOLECULAR STRUCTURES IN THE β-CYCLODEXTRIN- β-RESORCYLIC ACID SYSTEM
Abstract
It was found with the help of spectrophotometry, IR spectroscopy, X-ray phase analysis, and thermogravimetry, that new supramolecular structures in the β-cyclodextrin-β-resorcylic acid system are generated as a result of the spontaneous exothermic process. It was proved that the inclusion complexes of the host-guest type with 1:1 ratio between β-cyclodextrin and molecular form of β-resorcylic acid (or its monovalent anion) are formed through the van der Waals interactions of the aromatic ring of β-resorcylic acid with the inner hydrophobic cavity of β-cyclodextrin. It was shown that there are the partial displacement of water molecules from the inner cavity of the cyclic oligosaccharide and the complete immersion of β-resorcylic acid molecule inside it; the thermal stability of β-resorcylic acid increases.
Keywords
β-циклодекстрин,
β-резорциловая кислота,
супрамолекулярные структуры,
комплексы включения,
УФ и ИК спектроскопия,
рентгенофазовый анализ,
термогравиметрия,
β-cyclodextrin,
β-resorcylic acid,
supramolecular structures,
inclusion complexes,
UV-IR spectroscopy,
X-ray phase analysis,
thermogravimetry
About the Authors
L. A. Belyakova
A. A. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine
Russian Federation
Russian Federation
D. Yu. Lyashenko
A. A. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine
Russian Federation
Russian Federation
M. A. Dziazko
A. A. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine
Russian Federation
Russian Federation
E. I. Oranskaya
A. A. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine
Russian Federation
Russian Federation
Yu. I. Gornikov
A. A. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine
Russian Federation
Russian Federation
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Review
For citations:
Belyakova L.A., Lyashenko D.Yu., Dziazko M.A., Oranskaya E.I., Gornikov Yu.I. FORMATION OF SUPRAMOLECULAR STRUCTURES IN THE β-CYCLODEXTRIN- β-RESORCYLIC ACID SYSTEM. Zhurnal Prikladnoii Spektroskopii. 2017;84(3):450-456. (In Russ.)
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