A HIGHLY SELECTIVE FLUORESCENT CHEMOSENSOR FOR THE DETECTION OF PICRATE ANION BASED ON 1,8-NAPHTHALIMIDE DERIVATIVES
Abstract
The synthesis and spectral characteristics of a new fluorescent N-allyl-4-iminodi(N-benzylacetamide)-1,8-naphthalimide (Zabe) sensor were reported. The ability of this new compound to detect anions was evaluated by spectrophotometrically monitoring the changes in the fluoresence intensity performed on its N,N-dimethylformamide (DMF) solution. Compared to other anions examined, only picrate (Pic-) generated a prominent fluorescence quenching at 516 nm. No significant fluorescence change was observed in the presence of other anions. The emission quenching was due to the enhanced photoinduced electron transfer (PET) from the receptor to the excited state of the fluorophore upon the recognition of picrate. The chemosensor can be applied to the quantification of picrate with a linear range from 4.97×10-6 to 6.82×10-5 M and a detection limit of 6.6×10-7 M. Most importantly, this sensor can be utilized for the spectroscopic detection of picratein the presence of other competing anions. Moreover, the response time of the chemosensor is less than 1 min.
About the Authors
H. -L. Wu
School of Chemical and Biological Engineering, Lanzhou Jiaotong University
Russian Federation
Russian Federation
S. . Opeyemi Aderinto
School of Chemical and Biological Engineering, Lanzhou Jiaotong University
Russian Federation
Russian Federation
Y. -L. Xu
School of Chemical and Biological Engineering, Lanzhou Jiaotong University
Russian Federation
Russian Federation
H. . Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University
Russian Federation
Russian Federation
X. -Y. Fan
School of Chemical and Biological Engineering, Lanzhou Jiaotong University
Russian Federation
Russian Federation
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Review
For citations:
Wu H.-., Opeyemi Aderinto S., Xu Y.-., Zhang H., Fan X.-. A HIGHLY SELECTIVE FLUORESCENT CHEMOSENSOR FOR THE DETECTION OF PICRATE ANION BASED ON 1,8-NAPHTHALIMIDE DERIVATIVES. Zhurnal Prikladnoii Spektroskopii. 2017;84(1):33-38. (In Russ.)
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