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Dual-Channel More Flexible Salamo-Like Chemosensor for Fluorogenic Sensing of Copper Ion in Semi-Aqueous Medium
Abstract
The optical properties of the symmetric salamo-like chemical probe (H2CS) of Cu2+ were studied in EtOH/H2O (1:1, V/V) solution by UV-Vis and fluorescence spectroscopy. In the fluorescence spectrum, the coordination of Cu2+ with H2CS results in fluorescence quenching owing to the paramagnetic nature of Cu2+ ions. The binding constant of Cu2+ to the H2CS sensor was calculated as 1.17×1011 M–1 and LOD was obtained as 5.3×10–8 M. When Cu2+ ions were added, the UV-Vis spectra changed, obviously due to the electron transfer from sensor to metal bond, and a new absorption band appeared at 372 nm. When the ethylenediaminetetraacetic acid (EDTA) solution was added to the H2CS-Cu2+ solution, causing a large binding constant, with EDTA releasing the free sensor molecule and finally achieving a fluorescence shutdown phenomenon.
Keywords
salamo-like probe,
chemosensor,
synthesis,
two-channel detection,
ethylenediaminetetraacetic acid reversibility
Supporting agencies: This work was supported by the National Natural Science Foundation of China (21761018) and Overseas Visiting and Research Project for Outstanding Young Talents of Colleges and Universities (gxgwfx2019043), which is gratefully acknowledged.
About the Authors
R.-Y. Li
School of Chemical and Biological Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu
S.-X. Gao
School of Environmental and Municipal Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu
Ch. Liu
School of Chemical and Biological Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu
W.-K. Dong
School of Chemical and Biological Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu
Y.-J. Ding
College of Biochemical Engineering at Anhui Polytechnic University
China
China
Wuhu, Anhui
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Review
For citations:
Li R., Gao S., Liu Ch., Dong W., Ding Y. Dual-Channel More Flexible Salamo-Like Chemosensor for Fluorogenic Sensing of Copper Ion in Semi-Aqueous Medium. Zhurnal Prikladnoii Spektroskopii. 2022;89(1):137-145.
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