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Peculiarities of the Spectral Characteristics of Brassinosteroids of the 24-Epibrassinolide and 6-Deoxo-24-Epitheasterone Series in NMR Spectra in Deuteropyridine and Deuterochloroform

https://doi.org/10.47612/0514-7506-2022-89-2-162-169

Abstract

 Assignment of signals of the nuclei of hydrogen and carbon atoms in a group of steroids belonging to the group of 6-deoxo-24-epiteasterone and 24-epibrassinolide has been fulfilled using the two-dimensional Nuclear magnetic resonance spectroscopy methods. The effect of solvents on the chemical shift has been studied. 

About the Authors

A. V. Baranovsky
Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

 Minsk 



M. A. Aver’kova
Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

 Minsk 



R. P. Litvinovskaya
Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

 Minsk 



References

1. Р. П. Литвиновская, М. А. Аверькова, А. В. Барановский, В. А. Хрипач. ЖОрХ, 42, № 9 (2006) 1344—1350

2. M. Stoldt, A. Porzel, G. Adam, W. Brandt. Magn. Res. Chem., 35, N 9 (1997) 629—636

3. A. Porzel, V. Marquardt, G. Adam, G. Massiot, D. Zeigan. Mag. Res. Chem., 30, N 7 (1992) 651—657, doi: 10.1002/mrc.1260300714

4. T. Ando, M. Aburatani, N. Koseki, S. Asakawa, T. Mouri, H. Abe. Mag. Res. Chem., 31, N 1 (1993) 94—99, doi: 10.1002/mrc.1260310119

5. H. Chen, H. Feng, Y. Li, B. Jiang. Tetrahedron, 65, N 10 (2009) 2097—2101, doi: 10.1016/j.tet.2008.12.080

6. A. L. Hurski, A. G. Kukel, A. I. Liubina, A. G. Baradzenka, D. Straltsova, V. Demidchik, P. Drašar, V. N. Zhabinskii, V. A. Khripach. Steroids, 146 (2019) 92—98, doi: 10.1016/j.steroids.2019.03.010

7. V. N. Zhabinskii, D. A. Osiyuk, Y. V. Ermolovich, N. M. Chaschina, T. S. Dalidovich, M. Strnad, V. A. Khripach. Beilstein J. Org. Chem., 13 (2017) 2326—2331, doi: 10.3762/bjoc.13.229

8. R. P. Litvinovskaya, P. S. Minin, M. E. Raiman, G. A. Zhilitskaya, A.L. Kurtikova, K. G. Kozharnovich, M. V. Derevyanchuk, V. S. Kravets, V. A. Khripach. Chem. Nat. Comp., 49, N 3 (2013) 478—485

9. M. Anastasia, P. Allevi, P. Ciuffreda, A. Fiecchi, A. Scala. J. Org. Chem., 50, N 3 (1985) 321—325

10. A. G. Baradzenka, B. M. Barysau, A. L. Hurski, V. N. Zhabinskii, V. A. Khripach. Steroids, 101 (2015) 90—95, doi: 10.1016/j.steroids.2015.06.004

11. I. D. Alshakova, Y. V. Ermolovich, V. N. Zhabinskii, V. A. Khripach. Steroids, 97 (2015) 72—77, doi: 10.3762/bjoc.13.229

12. V. A. Khripach, V. N. Zhabinskii, D. V. Tsavlovskii. J. Ster. Biochem. Mol. Biol., 137 (2013) 345—354, doi: 10.1016/j.jsbmb.2013.01.016


Review

For citations:


Baranovsky A.V., Aver’kova M.A., Litvinovskaya R.P. Peculiarities of the Spectral Characteristics of Brassinosteroids of the 24-Epibrassinolide and 6-Deoxo-24-Epitheasterone Series in NMR Spectra in Deuteropyridine and Deuterochloroform. Zhurnal Prikladnoii Spektroskopii. 2022;89(2):162-169. (In Russ.) https://doi.org/10.47612/0514-7506-2022-89-2-162-169

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ISSN 0514-7506 (Print)