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Synthesis, Characterization, and Phosphate Anion Recognition Properties of Triethylene Glycol Bridged Oligourea Receptors
Abstract
Two triethylene glycol bridged oligourea receptors R1 and R2 were synthesized and characterized by 1H NMR, FT-IR, melting-point method and elemental analysis. The recognition properties of PO43– were studied by naked eye recognition and UV-vis spectroscopy. The Job’s plot analysis confirmed that the receptor R1 and PO43– formed a complex at a molar ratio of 3:2 while the binding ratio of R2 to PO43– was 1:1. The R1 recognized PO43– with a complexing constant of 1.46×105 M–1, and the complex constant of R2 recognizing PO43– was 2.75×105 M–1. In addition, the hydrogen bond between R1 and R2 with PO43– was examined with the method of alcohol effect by adding competitive solvent ethanol to the DMSO system. Furthermore, the recognition of PO43– by R1 and R2 was investigated through competitive measurements by adding other anions with the same concentration to the system. This study provides a simple and fast method for phosphate anion recognition.
Supporting agencies: The work was supported by the National Natural Science Foundation of China (Nos. 21301139, 21073139, 21103135), the China Scholarship Council (No. 201808615050), and Natural Science Basic Research Plan in Shaanxi Province of China (No. 2015JQ2043).
About the Authors
Z. Yang
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology;
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources
Russian Federation
Russian Federation
Xi’an, Shaanxi
J. Liu
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology
Russian Federation
Russian Federation
Xi’an, Shaanxi
S. Sun
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology
Russian Federation
Russian Federation
Xi’an, Shaanxi
X. Yu
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology
Russian Federation
Russian Federation
Xi’an, Shaanxi
X. Liu
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology;
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources
Russian Federation
Russian Federation
Xi’an, Shaanxi
S. Zhao
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology;
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources
Russian Federation
Russian Federation
Xi’an, Shaanxi
Zh. Yang
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology;
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources
Russian Federation
Russian Federation
Xi’an, Shaanxi
X. Jia
College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology;
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources
Russian Federation
Russian Federation
Xi’an, Shaanxi
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Review
For citations:
Yang Z., Liu J., Sun S., Yu X., Liu X., Zhao S., Yang Zh., Jia X. Synthesis, Characterization, and Phosphate Anion Recognition Properties of Triethylene Glycol Bridged Oligourea Receptors. Zhurnal Prikladnoii Spektroskopii. 2022;89(6):898.
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