SYNTHESIS AND CHARACTERIZATION OF A NOVEL LIGAND AND SPECTROSCOPIC STUDY OF THE FORMATION OF ITS COMPLEXES WITH DIFFERENT CATIONS AND THEIR SENSORY CHARACTERISTICS
Abstract
A new ligand (L), N,N′-bis(2-hydroxybenzyl)-1,2-diaminoethane, was synthesized and characterized. The sensing behavior of L toward various metal ions was investigated by spectrofluorometric and UV-Vis spectrophotometric methods. The sensor displayed selective and sensitive recognition toward Fe3+ and Fe2+ in acetonitrile. The fluorescence of L was quenched mainly by Fe3+ , and a considerable enhancement of fluorescence was observed in the presence of Zn2+ . Using multivariate hard modeling and stoichiometry, the concentration, spectral profiles, and formation constants of the studied complexes were calculated.
About the Authors
M. . Shariati-Rad
Razi University
Russian Federation
Russian Federation
M. . Karimi
Razi University
Russian Federation
Russian Federation
M. . Rezaeivala
Hamedan University of Technology
Russian Federation
Russian Federation
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Review
For citations:
Shariati-Rad M., Karimi M., Rezaeivala M. SYNTHESIS AND CHARACTERIZATION OF A NOVEL LIGAND AND SPECTROSCOPIC STUDY OF THE FORMATION OF ITS COMPLEXES WITH DIFFERENT CATIONS AND THEIR SENSORY CHARACTERISTICS. Zhurnal Prikladnoii Spektroskopii. 2017;84(6):1014(1)-1014(9). (In Russ.)
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