INFLUENCE OF INTERMOLECULAR INTERACTIONS AND AXIAL LIGANDS ON THE ABSORPTION SPECTRA OF METALLOPHTHALOCYANINES IN SOLID STATE MATRICES
Abstract
We have studied the influence of the structure of anionic axial ligands in phthalocyanine complexes of group IIIA and group IVA metals and intermolecular interactions on the absorption spectra of macroheterocycles in solutions, in an organic polymer, and nanoporous silicate gel matrices. It is shown that an effective process of substitution of the anionic ligands Cl- of the central metal ion for hydroxyl groups OH- takes place at the stage of synthesis and purification of metallophthalocyanines. The study of the solid-state nanoporous samples obtained by the sol-gel method showed that, in the organo-inorganic silicate material activated by hydroxoaluminum-phthalocyanine, the activator molecules are in a monomeric form. Optically homogeneous luminescent xerogel can be used in optical devices for the wavelength range adjacent to the near-IR region.
Keywords
металлофталоцианины,
золь-гель синтез,
нанопористые силикатные матрицы,
электронный спектр поглощения,
ИК спектр,
перелигандирование,
мономерные и агрегированные формы,
metallophthalocyanines,
sol-gel synthesis,
nanoporous silicate matrices,
electronic absorption spectrum,
IR spectrum,
re-liganding,
monomeric and aggregated forms
About the Authors
T. A. Pavich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Russian Federation
Russian Federation
S. M. Arabei
Belarusian State Agrarian and Technical University
Russian Federation
Russian Federation
K. N. Solovyov
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Russian Federation
Russian Federation
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Review
For citations:
Pavich T.A., Arabei S.M., Solovyov K.N. INFLUENCE OF INTERMOLECULAR INTERACTIONS AND AXIAL LIGANDS ON THE ABSORPTION SPECTRA OF METALLOPHTHALOCYANINES IN SOLID STATE MATRICES. Zhurnal Prikladnoii Spektroskopii. 2018;85(1):5-13. (In Russ.)
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