X-RAY PHOTOELECTRON SPECTROSCOPY OF CHLOROMETALLATE IONIC LIQUIDS: SPECIATION AND ANION BASICITY
Abstract
X-ray photoelectron spectroscopy is used to detect the formation of different chlorometallate anions and to differentiate the electronic environment of each element present in chlorometallate anions. The impact of the degree of the charge delocalization of chlorometallate anions on the Cl 2p binding energy is demonstrated in detail. The basicity of chlorostannate and chloroferrate anions is estimated based upon the measured N 1s binding energy. It is found that chlorostannate and chloroferrate anions can be considered as the least basic anions.
About the Authors
Sh. . Men
School of Material Science and Engineering, Shenyang Ligong University; Institute of Applied Ecology, Chinese Academy of Sciences
Russian Federation
Russian Federation
J. . Jiang
School of Mechanical Engineering and Automation, Northeastern University
Russian Federation
Russian Federation
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Review
For citations:
Men Sh., Jiang J. X-RAY PHOTOELECTRON SPECTROSCOPY OF CHLOROMETALLATE IONIC LIQUIDS: SPECIATION AND ANION BASICITY. Zhurnal Prikladnoii Spektroskopii. 2018;85(1):63-68. (In Russ.)
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