Preview

Zhurnal Prikladnoii Spektroskopii

Advanced search

RAMAN AND TIME GATED-LIF SPECTROSCOPY FOR THE IDENTIFICATION OF PAINTING MATERIALS

Abstract

A detailed characterization of painting materials by Raman and time gated laser induced fluorescence (TG-LIF) spectroscopy is proposed. The complementary capabilities of the considered techniques are investigated on a set of laboratory samples realized simulating real artworks. The achieved results confirmed the capability of Raman spectroscopy to characterize pigments and dyes, while the identification of binders and protective materials proved to be difficult because of their intense fluorescence. For this reason, the analyzed samples were also classified by TG-LIF spectroscopy in terms of their characteristic emission wavelengths and decay times. The complementary capabilities of Raman and TG-LIF are confirmed, and a correlation between their results is assessed in order to obtain a complete characterization of the analyzed samples.

About the Authors

M. . Romani
Universit degli studi di Roma “Tor Vergata”
Russian Federation


S. . Almaviva
ENEA, Italian National Agency for New Technologies
Russian Federation


F. . Colao
ENEA, Italian National Agency for New Technologies
Russian Federation


R. . Fantoni
ENEA, Italian National Agency for New Technologies
Russian Federation


M. . Marinelli
Universit degli studi di Roma “Tor Vergata”
Russian Federation


A. . Pasqualucci
Universit degli studi di Roma “Tor Vergata”
Russian Federation


A. . Puiu
ENEA, Italian National Agency for New Technologies
Russian Federation


G. . Verona-Rinati
Universit degli studi di Roma “Tor Vergata”
Russian Federation


References

1. G. Bitossi, R. Giorgi, M. Mauro, B. Salvadori, L. Dei, Appl. Spectrosc. Rev., 40, No. 3, 187-228 (2005).

2. G. Artioli, Scientific Methods and Cultural Heritage: an Introduction to the Application of Materials Science to Archaeometry and Conservation Science, Oxford, Oxford University Press (2010).

3. A. Deneckerea, M. De Reub, M. P. J. Martensc, K. De Coened, B. Vekemansa, L. Vinczea, De Maeyerd, P. Vandenabeelee, L. Moensa, Spectrochim. Acta A, 80, No. 1, 125-132 (2011).

4. C. Ricci, I. Borgia, B. G. Brunetti, C. Miliani, A. Sgamellotti, C. Seccaroni, P. Passalacqua, J. Raman. Spectrosc., 35, No. 8-9, 616-621 (2004).

5. I. M. Bell, J. H. Clark, P. J. Gibbs, Spectrochim. Acta A, 53, No. 12, 2159-2179 (1997).

6. G. Burrafato, M. Calabrese, A. Cosentino, A. M. Gueli, S. O. Troja, A. Zuccarello, J. Raman. Spectrosc., 35, No. 10, 879-886 (2004). 327-9

7. P. Vandenabeele, B. Wehling, L. Moens, H. Edwards, M. De Reu, G. Van Hooydonk, Anal. Chim. Acta, 407, No. 1-2, 261-274 (2000).

8. A. Nevin, G. Spoto, D. Anglos, Appl. Phys. A: Mater., 106, No. 2, 339-361 (2012).

9. D. Anglos, M. Solomidou, I. Zergioti, V. Zaffiropulos, T. G. Papazoglouand C. Fotakis., Appl. Spectrosc., 50, 1331-1334 (1996).

10. T. Miyoshy, Y. Matasuda, Jpn. J. Appl. Phys., 26, No. 2, 239-245 (1987).

11. R. Fantoni, L. Caneve, F. Colao, L. Fiorani, A. Palucci, R. Dell’Erba, V. Fassina, J. Cult. Herit., 14, No. 3, 59-65 (2013).

12. A. Cesaratto, C. D’Andrea, A. Nevin, G. Valentini, F. Tassone, R. Alberti, T. Frizzi, D. Comelli, Anal. Methods, 6, 130-138 (2014).

13. A. Nevin, D. Comelli, G. Valentini, D. Anglos, A. Burnstock, S. Cather, R. Cubeddu, Anal. Bioanal. Chem., 388, No. 8, 1897-1905 (2007).

14. A. P. Shreve, N. J. Cherepy, R. A. Mathies, Appl. Spectrosc., 46, No. 4, 707-711 (1992).

15. R. A. Goodall, J. Hall, H. G. M. Edwards, R. J. Sharer, R. Viel, P. M. Fredericks, J. Archaeol. Sci., 34, 666-673 (2007).

16. M. Romani, F. Colao, R. Fantoni, M. Guiso, M. L. Santarelli, J. Appl. Laser Spectrosc., 1, 29-36 (2014).

17. M. Marinelli, A. Pasqualucci, M. Romani, G. Verona-Rinati, J. Cult. Herit., 23, 98-105 (2017).

18. I. Borgia, R. Fantoni, C. Flamini, T. M. Di Palma, A. Giardini Guidoni, A. Mele, Appl. Surf. Sci., 127-128, 95-100 (1998).

19. F. N. Jones, W. Mao, P. D. Ziemer, F. Xiao, J. Hayes, M. Golden, Prog. Org. Coat., 52, No. 1, 9-20 (2005).

20. P. Symour, The Artist’s Handbook, Arcturus Publishing Limited, London (2003).

21. M. Bacci, M. Picollo, G. Trumpy, M. Tsukada, D. Kunzelman, J. Am. Inst. Conserv., 46, No. 1, 27-37 (2007).

22. L. Fiorani, L. Caneve, F. Colao, R. Fantoni, P. Ortiz, M. A. Gòmez, M. A.Vàzquez, Adv. Mater. Res., 133-134, 253-258 (2010).

23. N. C. Scherrer, S. Zumbuhel, F. Delavy, A. Fritsch, R. Kuehnen, Spectrochim. Acta A, 73, 505-524 (2009).

24. I. M. Bell, R. J. H. Clark, P. J. Gibbs, Spectrochim. Acta. A, 53A, 2159-79 (1997).

25. M. C. Caggiani, A. Cosentino, A. Mangone, Microchem. J., 129, 123-132 (2016).

26. M. Romani, M. Marinelli, A. Pasqualucci, G. Verona-Rinati, Lasers in the Conservation of Artworks XI, Proc. Int. Conf. LACONA XI, Kraków, Poland, 20-23 September 2016, NCU Press, Toruń (2017).

27. F. Pozzi, J. R. Lombardi, M. Leona, Herit. Sci., 1, 23 (2013).


Review

For citations:


Romani M., Almaviva S., Colao F., Fantoni R., Marinelli M., Pasqualucci A., Puiu A., Verona-Rinati G. RAMAN AND TIME GATED-LIF SPECTROSCOPY FOR THE IDENTIFICATION OF PAINTING MATERIALS. Zhurnal Prikladnoii Spektroskopii. 2019;86(2):327(1)-327(9). (In Russ.)

Views: 328


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0514-7506 (Print)