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RAMAN SPECTROSCOPY APPLICATION FOR ANALYZING DIAMOND COATINGS ON HARD ALLOY

Abstract

The single- and multilayer coatings of micro- and nanocrystalline diamond were deposited on cemented carbide substrates (WC + 6 wt.% Co alloy) in a microwave plasma of methane-hydrogen and methane-hydrogen-nitrogen mixtures. The barrier tungsten layers were used to improve adhesion of the diamond coatings on the substrates. Raman spectroscopy was used to study properties of the nano- and microcrystalline diamond coatings depending on the deposition parameters. Data on structural transformations of the coatings under different tribological contact conditions were obtained, and the secondary nucleation processes on different diamond faces during the deposition from the gas phase were investigated.

About the Authors

A. A. Khomich
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences; V. A. Kotelnikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences
Russian Federation


E. E. Ashkinazi
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences; National Research Nuclear University MEPhI
Russian Federation


V. G. Ralchenko
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences; National Research Nuclear University MEPhI; Harbin Institute of Technology
Russian Federation


V. S. Sedov
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences; National Research Nuclear University MEPhI
Russian Federation


R. A. Khmelnitskii
P. N. Lebedev Physical Institute, Russian Academy of Sciences
Russian Federation


O. N. Poklonskaya
Belarussian State University
Russian Federation


M. V. Kozlova
M. V. Lomonosov Moscow State University
Russian Federation


A. V. Khomich
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences; V. A. Kotelnikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences; National Research Nuclear University MEPhI
Russian Federation


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Review

For citations:


Khomich A.A., Ashkinazi E.E., Ralchenko V.G., Sedov V.S., Khmelnitskii R.A., Poklonskaya O.N., Kozlova M.V., Khomich A.V. RAMAN SPECTROSCOPY APPLICATION FOR ANALYZING DIAMOND COATINGS ON HARD ALLOY. Zhurnal Prikladnoii Spektroskopii. 2017;84(2):295-302. (In Russ.)

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