STRUCTURE AND DYNAMICS OF COMPLEX IONS IN YbCl3-MCl (M = K, Cs) MELTS BASED ON RAMAN SPECTROSCOPY DATA
Abstract
The method of Raman spectroscopy has been used to obtain in situ information on the structure of high-temperature ion melts of YbCl3-MCl (M = K, Cs). The force constant of the Yb–Cl bond and the orientational relaxation time of the YbCl63– complex ionic group are calculated. Empirical equations describing the correlation between the dynamic characteristics of the YbCl63– complex and the conductivity of the studied melts are obtained.
About the Author
I. D. Zakir’yanova
Institute of High-Temperature Electrochemistry, Ural Branch of Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin
Russian Federation
Russian Federation
22 S. Kovalevskaya Str., Ekaterinburg, 620219; Ekaterinburg, 620002
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Review
For citations:
Zakir’yanova I.D. STRUCTURE AND DYNAMICS OF COMPLEX IONS IN YbCl3-MCl (M = K, Cs) MELTS BASED ON RAMAN SPECTROSCOPY DATA. Zhurnal Prikladnoii Spektroskopii. 2019;86(3):368-373. (In Russ.)
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