UV-VISIBLE SPECTROPHOTOMETRY WITH ARSENAZO III FOR THE DETERMINATION OF SAMARIUM
Abstract
UV-visible spectrophotometry with Arsenazo III is used to determine the samarium concentration. The results confirm that the concentration of Sm3+ in the aqueous solution from 2.7×10- 6 to 10.8×10- 6 mol/L obeys the Lambert-Beer law. The quantitative relationship between the absorbance and concentrations of Ca2+ and F- in the solution with 2.7×10- 6 mol/L Sm3+ has been obtained. The absorbance of the solution with 10.8×10- 6 mol/L Sm3+ is found to be 0.58, which is not affected by the concentrations of Ca2+ and F-. So, if the concentration of Ca2+ and F- were known, the quantitative relationship between absorbance and Sm3+ concentration can be obtained, which is convenient for determining the Sm3+ concentration in aqueous solution with Ca2+ and F- by UV-visible spectrophotometry.
Supporting agencies: The authors would like to express their gratitude to the National Natural Science Foundation of China for financial support (No. 51374017, No.51774029 and U1460201).
About the Authors
Xing-Min Guo
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing
China
Beijing 100083
China
Beijing 100083
Qi-Cao Yan
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing
China
Beijing 100083
China
Beijing 100083
Xiao-Ting Meng
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing
China
Beijing 100083
China
Beijing 100083
Rui-Xin Ma
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing
China
Beijing 100083
China
Beijing 100083
References
1. Z. Q. Xue, L. Liu, Z. Liu, M. Li, D. Lee, R. J. Chen, Y. Q. Guo, A. R. Yan, Scr. Mater., 113, 226–230 (2016).
2. W. Sun, M. G. Zhu, Y. K. Fang, Z. Y. Liu, H. S. Chen, Z. H. Guo, W. Li, J. Magn. Magn. Mater., 378, 214–216 (2015).
3. M. Kuru, O. Sahin, S. Ozarslan, A. E. Ozmetin, J. Alloy. Compd., 694, 726–732 (2017).
4. R. K. Singh, S. V. Kamat, R. P. Mathur, J. Magn. Magn. Mater., 379, 300–304 (2015).
5. V. I. Kushnirenko, M. V. Sopinskyy, E. G. Manoilov, V. S. Khomchenko, J. Alloy. Compd., 451, 209–211 (2008).
6. H. Hakala, P. Liitti, K. Puukka, J. Peuralahti, K. Loman, J. Karvinen, P. Ollikka, A. Ylikoski, V. M. Mukkala, J. Hovinen, Inorg. Chem. Commun., 5, 1059–1062 (2002).
7. J. D. Castillo, A. C. Yanes, S. Abe, P. F. Smet, J. Alloy. Compd., 635, 136–141 (2015).
8. T. Saito, H. Kitazima, J. Magn. Magn. Mater., 32, 2154–2157 (2011).
9. G. Cordoba, C. Caravaca, J. Electroanal. Chem., 572, 145–151 (2004).
10. T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 2517–2521 (2003).
11. T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 46, 2537–2544 (2001).
12. T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 901–906 (2003).
13. L. Massot, P. Chamelot, P. Taxil, Electrochim. Acta, 50, 5510–5517 (2005).
14. Y. H. Liu, Y. D. Yan, M. L. Zhang, J. N. Zheng, Y. Zhao, P. Wang, T. Q. Yin, X. Y. Jing, W. Han, Electrochim. Acta, 163, D672–D681 (2016).
15. Y. H. Liu, Y. D. Yan, M. L. Zhang, Y. Liang, J. M. Qu, P. Li, D. B. Ji, Y. Xue, X. Y. Jing, W. Han, Electrochim. Acta, 249, 278–289 (2017).
16. Q. C. Yan, X. M. Guo. J. Alloy. Compd., 747, 994–1001 (2018).
17. X. M. Guo, Q. C. Yan, China Patent CN201610183598.1 (2016).
18. Q. C. Yan, X. M. Guo, Solid State Commun., 272, 63–66 (2018).
19. R. Schramm, Phys. Sci. Rev., 1, 1–17 (2016).
20. L. O. Dubenskaya, G. D. Levitskaya, N. P. Poperechnaya, J. Anal. Chem., 60, 304–309 (2005).
21. É. Biémont, Recent Phys. Scr., 119, 55–60 (2005).
22. H. Kunzendorf, H. A. Wollenberg, Nucl. Instrum. Methods, 87, 197–203 (1970).
23. E. Woznicka, M. Kopacz, M. Umbreit, J. Klos, J. Inorg. Biochem., 101, 774–782 (2007).
24. N. T. Birgani, S. Elhami, J. AOAC Int., 100, 224–229 (2017).
25. B. Debus, M. Sliwa, H. Miyasaka, J. Abe, C. Ruckebusch, Chemometr. Intell. Lab., 128, 101–110 (2013).
26. T. I. Shabatina, A. V. Vlasov, E. V. Vovk, D. J. Stufkens, G. B. Sergeev, Spectrochim. Acta A, 56, 2539–2543 (2000).
27. M. B. Kime, D. Makgoale, Chem. Eng.Commun., 203, 1648–1655 (2016).
28. N. H. Choi, S. K. Kwon, H. Kim, J. Electrochem. Soc., 160, A973–A979 (2013).
29. H. Rohwer, E. Hosten, Anal. Chim. Acta, 339, 271–277 (1997).
30. H. Rohwer, N. Collier, E. Hosten, Anal. Chim. Acta, 314, 219–223 (1995).
31. B. Buděšínský, Collect. Czech. Chem. Commun., 28, 1858–1866 (1963).
32. N. C. Kendrick, Anal. Biochem., 76, 487–501 (1976).
33. R. Borissova, E. Mitropolitska, Talanta, 24, 49–51 (1979).
34. L. F. Qiu, X. H. Kang, T. S. Wang, Sep. Sci. Technol., 11, 32–35 (1991).
35. M. D’Orazio, S. Tonarini, Anal. Chim. Acta, 351, 325–335 (1997).
36. Y. J. Dong, K. Gai, X. X. Gong, J. Chongqing Normal Un-ty (Nat. Sci. Ed.), 21, 43–45 (2004).
37. Y. L. Shi, E. Edward, E. R. Van, J. Chem. Soc. Dalton Trans., 967–974 (1998).
38. K. Matharu, S. K. Mittal, S. K. A. Kumar, Spectrochim. Acta A, 145, 165–175 (2015).
39. X. Z. Yang, Hydrometallurgy China, 26, 109–112 (2007).
Review
For citations:
Guo X., Yan Q., Meng X., Ma R. UV-VISIBLE SPECTROPHOTOMETRY WITH ARSENAZO III FOR THE DETERMINATION OF SAMARIUM. Zhurnal Prikladnoii Spektroskopii. 2019;86(3):492(1)-492(7).
Views: 417
Email this article 