SPECTRAL-LUMINESCENT CHARACTERISTICS OF THE MARKERS OF THE FLUORESCEIN FAMILY IN REVERSE MICELLAS OF DIFFERENT SIZES
Abstract
We investigate the spectral-luminescent characteristics of eosin, erythrosin, and rose bengal molecules in reverse micelles of sodium bis(2-ethylhexyl)sulfosuccinate of sodium. It has been established that the incorporation of dye molecules into reverse micelles causes an increase in their hydrodynamic radii Rh. Meanwhile, a linear dependence of this increase ΔRh on the degree of hydration w is observed. Magnification of Rh causes a shift in the absorption and fluorescence spectra as well as an additional Stokes shift. It is shown that with increasing Rh, the ratio of the dipole moments of the excited and ground states μe/μg also increases.
About the Authors
O. I. Volkova
M. V. Lomonosov Moscow State University
Russian Federation
Moscow, 119991
Russian Federation
Moscow, 119991
A. A. Kuleshova
M. V. Lomonosov Moscow State University
Russian Federation
Moscow, 119991
Russian Federation
Moscow, 119991
A. M. Saletsky
M. V. Lomonosov Moscow State University
Russian Federation
Moscow, 119991
Russian Federation
Moscow, 119991
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Review
For citations:
Volkova O.I., Kuleshova A.A., Saletsky A.M. SPECTRAL-LUMINESCENT CHARACTERISTICS OF THE MARKERS OF THE FLUORESCEIN FAMILY IN REVERSE MICELLAS OF DIFFERENT SIZES. Zhurnal Prikladnoii Spektroskopii. 2020;87(5):790-795. (In Russ.)
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