Study of emulsion morphology by electron spectroscopy
Abstract
The morphology of two types of emulsions - milk fat in water and liquid paraffin in isopropyl alcohol of various concentrations - was studied by electron spectroscopy in the UV and visible ranges. The developed method is based on the analysis of the scattering component of electromagnetic radiation passing through the sample, which allows determining the size of the scattering particles (droplets) and their size distribution. It was found that particle sizes increase with an increase in the concentration of the dispersed phase. That conclusion was confirmed by independent research methods: dynamic light scattering and optical microscopy.
About the Authors
A. I. MarkovaRussian Federation
Tver', 170002.
M. V. Yarusov
Russian Federation
Tver', 170002.
S. D. Khizhnyak
Russian Federation
Tver', 170002.
P. M. Pakhomov
Russian Federation
Tver', 170002.
References
1. А. А. Абрамзон. Поверхностно-активные вещества: свойства и применение, Химия, Ленинград (1981)
2. Ph. Sherman. Emulsion Science, Academic Press, London—New York (1968)
3. T. G. Mason, J. N. Wilking, K. Meleson, C. B. Chang, S. M. Graves. J. Phys.: Condens. Matter, 18 (2006) 635—666
4. J. P. Kratohvil. Analyt. Chem., 38, N 2 (1966) 517—526
5. В. Е. Эскин. Рассеяние света растворами полимеров и свойства макромолекул, Наука, Ленинград (1986)
6. D. Clausse, F. Gomez, C. Dalmazzone, C. Noik. J. Coll. Interface Sci., 287, N 2 (2005) 694—703
7. К. С. Шифрин. Рассеяние света в мутной среде, гос. изд., Москва-Ленинград (1951)
8. S. D. Khizhnyak, M. N. Malanin, K.-J. Eichhorn, P. M. Pakhomov. Polym. Sci., 50В, N 5-6 (2008) 158—164
9. J. Dechant. Ultrarotspektroskopische Untersuchungen an Polymeren, Akademie Verlag, Berlin (1972)
10. P. M. Pakhomov, S. D. Khizhnyak, S. Yu. Zharov, K.-J. Eichhorn. Fibre Chem., 40, N 3 (2008) 253—265
11. P. M. Pakhomov, E. V. Kruglova, S. D. Khizhnyak. Polym. Sci., 42B, N 5-6 (2000) 169—174
12. P. M. Pakhomov, M. N. Malanin, E. V. Kruglova, S. D. Khizhnyak. Polym. Sci., 43B, N 3-4 (2001) 120—123
13. П. M. Пахомов, M. Н. Маланин, С. Д. Хижняк. Высокомол. соед., 47B, N 6 (2005) 1066—1072
14. V. E. Sitnikova, S. D. Khizhnyak, P. M. Pakhomov. J. Appl. Chem., 87, N 6 (2014) 810—817
15. П. М. Пахомов, С. Д. Хижняк, В. Е. Ситникова. Журн. прикл. спектр., 84, № 5 (2017) 780—785 [P. М. Pakhomov, S. D. Khizhnyak, V. E. Sitnikova. J. Appl. Spectr., 84, N 5 (2017) 837—842]
16. К. П. Мищенко, А. А. Равдель. Краткий справочник физико-химических величин, Химия, Ленинград (1974)
Review
For citations:
Markova A.I., Yarusov M.V., Khizhnyak S.D., Pakhomov P.M. Study of emulsion morphology by electron spectroscopy. Zhurnal Prikladnoii Spektroskopii. 2020;87(6):880-885. (In Russ.)