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Limits of Detection of Chemical Elements in an Aqueous Aerosol in Filament-Induced Breakdown Spectroscopy
Abstract
The capabilities offilament-induced breakdown spectroscopy for the analysis of the elemental composition of water aerosols were estimated. The diameter of water aerosol droplets in the atmosphere was 0.8-2.0 pm. The emission lines of the chemical elements were excited by filamentation offemtosecond laser pulses (60 fs, 800 nm, 4.4 mJ) in the weak focusing mode by a lens with a focal length of 500 mm. The obtained limits of detection for Al (396.15 nm), Ba (553.35 nm), Ca (422.67 nm), Mg (285.21 nm), Na (588.99 nm), and Mn (403.08 nm) in a water aerosol were 12.1, 41.7, 10.0, 7.3, 0.7, and 32.2 mg/L, respectively.
About the Authors
S. S. Golik
Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of Sciences; Far Eastern Federal University
Russian Federation
Russian Federation
Vladivostok, 690041; Russky Island, Vladivostok, 690922
A. Yu. Mayor
Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of Sciences; Far Eastern Federal University
Russian Federation
Russian Federation
Vladivostok, 690041; Russky Island, Vladivostok, 690922
V. V. Lisitsa
Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of Sciences; Far Eastern Federal University
Russian Federation
Russian Federation
Vladivostok, 690041; Russky Island, Vladivostok, 690922
Yu. S. Tolstonogova
Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of Sciences; Far Eastern Federal University
Russian Federation
Russian Federation
Vladivostok, 690041; Russky Island, Vladivostok, 690922
A. A. Ilyin
Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of Sciences; Far Eastern Federal University
Russian Federation
Russian Federation
Vladivostok, 690041; Russky Island, Vladivostok, 690922
А. V. Borovskiy
Far Eastern Federal University
Russian Federation
Russian Federation
Russky Island, Vladivostok, 690922
O. A. Bukin
Far Eastern Federal University
Russian Federation
Russian Federation
Russky Island, Vladivostok, 690922
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Review
For citations:
Golik S.S., Mayor A.Yu., Lisitsa V.V., Tolstonogova Yu.S., Ilyin A.A., Borovskiy А.V., Bukin O.A. Limits of Detection of Chemical Elements in an Aqueous Aerosol in Filament-Induced Breakdown Spectroscopy. Zhurnal Prikladnoii Spektroskopii. 2021;88(2):275-281. (In Russ.)
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