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Novel Tridentate Bisoxime Chemosensor for Selective Recognition of Cu2+and Zn 2+ with Different Mechanisms
Abstract
A novel tridentate bisoxime chemosensor HL has been developed as a two-in-one platform for colorimetric recognition of Cu2+ (from blue to green), and fluorescent recognition of Cu2+ fluorescence quenching) and Zn2+ (fluorescence enhancement) in aqueous solution (CH3OH/H2O, 9:1, v/v). The UV-Vis and fluorescent spectra, IR, NMR, and density functional theory (DFT) calculations indicate that the recognition mechanism for quenching the fluorescence of the HL sensor for Cu2+ is a photoinduced electron transfer process (PET) between the recognition group (phenolic hydroxyl group and Schiff-base group) of the sensor and the signal reporter group (benzene ring), and the enhanced fluorescence recognition mechanism of the HL sensor for Zn2+ is of its hindered PET process.
Keywords
molecule sensor,
colorimetric recognition,
UV visible recognition,
fluorescence recognition,
Cu2+ and Zn22 ions,
density functional theoty calculation
Supporting agencies: This work was supported by Youth Science Foundation of Gansu Province (20JR5RF611), the National Natural Science Foundation of China (21761018) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706), three of which are gratefully acknowledged
About the Authors
W.-T. Guo
School of Chemical and Biological Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu, 730070
Y.-D. Peng
School of Chemical and Biological Engineering at Lanzhou Jiaotong University; Department of Energy Engineering, Wuwei Occupational College
China
China
Lanzhou, Gansu, 730070; Wuwei 733000
Y. Zhang
School of Chemical and Biological Engineering at Lanzhou Jiaotong University
China
China
Lanzhou, Gansu, 730070
H. Zhang
Wuwei Occupational College
China
China
Department of Energy Engineering
Wuwei 733000
Y.-L. Jiang
School of Chemical Engineering and Energy at Zhengzhou University
China
China
Zhengzhou 45000l, Henan
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Review
For citations:
Guo W., Peng Y., Zhang Y., Zhang H., Jiang Y. Novel Tridentate Bisoxime Chemosensor for Selective Recognition of Cu2+and Zn 2+ with Different Mechanisms. Zhurnal Prikladnoii Spektroskopii. 2021;88(2):339(1)-339(9).
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