|Generate QR code
Open Access
Subscription Access
Calculation and comparative analysis of ir spectra of a number of brassinolides with different structure of their side chain
Abstract
To establish spectro-structural correlations of practically important biologically active steroid phytohormones, namely, molecules (22S,23S)-24-epibrassinolide, (22S,23S)-28-homobrassinolide and homobrassinolide, a comparative analysis of experimental IR spectra and theoretical spectral absorption curves of these molecules with similar chemical structure has been done. This made it possible to evaluate the influence of structural features within the side chain of the studied molecules on the formation of IR spectra and to establish a connection between their structural differences and the observed changes in IR spectra in the range of 1500–950 cm–1 .
About the Authors
V. M. Andrianov
Belarusian State Agrarian Technical University
Belarus
Belarus
Minsk
M. V. Korolevich
Belarusian State Agrarian Technical University
Belarus
Belarus
Minsk
References
1. Y. Zhou, C. Garcia-Prieto, D. A. Carney, R. Xu, H. Pelicano, Y. Kang, W.Yu, C. Lou, S. Kondo, J. Liu, D. M. Harris, Z. Estrov, M. J. Keating, Z. Jin, P. Huang. J. Natl. Cancer Inst., 97 (2005) 1781—1785
2. T. Nakata, T. Yamada, S. Taji, H. Ohishi, S. Wada, H. Tokuda, K. Sakuma, R. Tanaka. Bioorg. Med. Chem., 15 (2007) 257—264
3. E. Hovenkamp, I. Demonty, J. Plat, D. Lutjohann, R. P. Mensink, E. A. Trautwein. Prog. Lipid Res., 47 (2008) 37—49
4. T.-M. Wang, T. Hojo, F.-X. Ran, R.-F. Wang, R.-Q. Wang, H.-B. Chen, J. R. Cui, M. Y. Shang, S. Q. Cai. J. Nat. Prod., 70 (2007) 1429—1433
5. V. A. Khripach, V. N. Zhabinskii, A. E. de Groot. Brassinosteroids: a New Class of Plant Hormones, San Diego, CA: Academic Рress (1999)
6. J. L. Nemhauser, J. Chory. J. Exp. Bot., 55 (2004) 265—270
7. Y. Hu, F. Bao, J. Li. Plant J., 24 (2000) 693—701
8. S. Drosihn, A. Porzel, W. Brandt J. Mol. Model, 7 (2001) 34—42
9. J. Malıkova, J. Swaczynova, Z. Kolar, M. Strnad. Phytochemistry, 69 (2008) 418—426
10. A. Yu. Misharin, A. R. Mehtiev, V. N. Zhabinskii, V. A. Khripach, V. P. Timofeev, Ya. V. Tkachev. Steroids, 75 (2010) 287—294
11. N. A. Borisevich, I. V. Skornyakov, V. A. Khripach, G. B. Tolstorozhev, V. N. Zhabinsky. J. Appl. Spectr, 74 (2007) 673—680
12. N. A. Borisevich, D. K. Buslov, V. N. Zhabinsky. V. A. Khripach. J. Appl. Spectr, 76 (2009) 617—622
13. N. A. Borisevich, D. K. Buslov. J. Appl. Spectr., 77 (2010) 529—534
14. V. M. Andrianov, M. V. Korolevich. J. Appl. Spectr., 75 (2008) 768—775
15. В. М. Андрианов, М. В. Королевич. В сб. ст. междунар. науч. конф. “Молекулярные, мембранные и клеточные основы функционирования биосистем”, 23—25 июня 2010 г., Минск, 1 (2010) 302—304
16. V. M. Andrianov, M. V. Korolevich, A. A. Velchenko. J. Appl. Spectr., 86, N 6, 965—974
17. L. Kutschabsky, G. Adam, H.-M. Vorbrodt. Z. Chem., 30 (1990) 136—145
18. L. Kutschabsky, G. Reck. Private Communication to the Cambridge Structural Database, deposition number CCDC (2003) 201799
19. М. В. Королевич. Аналитическая инфракрасная спектроскопия сахаридов, дис. ... д-ра физ.-мат. наук, Минск (2009)
Review
For citations:
Andrianov V.M., Korolevich M.V. Calculation and comparative analysis of ir spectra of a number of brassinolides with different structure of their side chain. Zhurnal Prikladnoii Spektroskopii. 2021;88(4):513-520. (In Russ.)
Views: 375
Email this article 