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Estimation of the polarity of stationary phases for gas-liquid chromatography based on spectral parameters
Abstract
The estimation of the applicability and the choice of the scale of quantitative one-parameter evaluation of the polarity of stationary liquid phases were carried out for gas-liquid chromatography. The absorption and luminescence spectra of five indicators including coumarin 153, coumarin 314, coronene, 4-dicyanomethylene-2-methyl-6-[4-(di-methylamino)-styryl]-4H-pyran (DCM), 3-aminophthalimide have been obtainned in solvents of different polarity at room temperature. The dependence of the wavelength of the fluorescence and absorption maxima on the polarity of the medium was evaluated. Various spectroscopic polarity scales are compared. The fluorescent coronene scale has been shown to be the most appropriate. This scale was used to assess the polarity of some widespread phases (squalane, polydimethylsiloxane liquid PMS-100, 3,3'-oxydipropionitrile, 2-ethyl-hexylsebacinate, etc.) for gas-liquid chromatography. This approach has been shown to be promising for preliminary selection of chromatographic stationary phases.
About the Authors
V. I. Beketov
Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
M. V. Belkov
Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
N. B. Zorov
Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
S. N. Lanin
Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
P. N. Nesterenk
Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
P. P. Pershukevich
Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
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Review
For citations:
Beketov V.I., Belkov M.V., Zorov N.B., Lanin S.N., Nesterenk P.N., Pershukevich P.P. Estimation of the polarity of stationary phases for gas-liquid chromatography based on spectral parameters. Zhurnal Prikladnoii Spektroskopii. 2021;88(4):569-575. (In Russ.)
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