|Generate QR code
Open Access
Subscription Access
Nonlinear Optical Properties of Novel Metallophthalocyanine
Abstract
Detailed measurements of nonlinear optical properties and optical limiting for four phthalocyanine (Pc) derivatives (PcCo, PcCu, PcMn, and PcSi) are reported. The nonlinear optical properties were investigated using a Z-scan technique with a continuous-wave argon ion laser at 488 and 514.5 nm, and with a 532-nm pulsed Nd:YAG laser. All Pcs exhibited strong nonlinear properties and low optical-limiting thresholds. The nonlinear absorption coefficient, the sign and magnitude of the nonlinear refractive index, and the thirdorder nonlinear susceptibilities of each compound were calculated. Refractive nonlinear effects are the most dominant for continuous laser excitation and are mainly attributed to thermal effects, whereas the reverse saturation absorption coefficient may have an electronic origin. Threshold values indicated that the Pc derivatives are promising materials for optical-limiting applications.
About the Authors
F. A. Alawainati
University of Bahrain
Bahrain
Bahrain
Department of Physics
P.O. Box 32038
H. Manaa
University of Bahrain
Bahrain
Bahrain
Department of Physics
P.O. Box 32038
F. Z. Henari
Royal College of Surgeons in Ireland, Medical University of Bahrain
Bahrain
Bahrain
Department of Medical Sciences
Z. Biyiklioglu
Karadeniz Technical University
Turkey
Turkey
Department of Chemistry
Trabzon 61080
T. Arslan
Giresun University
Turkey
Turkey
Department of Chemistry
Giresun 28200
A. Jaafar
University of Bahrain
Bahrain
Bahrain
Department of Physics
P.O. Box 32038
References
1. K. Manjunatha, R. Dileep, G. Umesh, B. Bhat, Opt. Laser Technol., 52, 103–108 (2013).
2. S. M. O'Flaherty, S. V. Hold, M. J. Cook, T. Torres, Y. Chen, M. Hanack, W. Blau, Adv. Mater., 15, 19–32 (2003).
3. G. De la Torre, C. G. Claessens, T. Torres, Chem. Commun., 20, 2000–2015 (2007).
4. C. Claessens, W. Blau, M. Cook, M. Hanack, R. Nolte, T. Torres, D. Woehrle, Opt. Properties Mon. Chem., 132, 3–11 (2001).
5. S. Hughes, J. M. Burzler, Phys. Rev. A, 56, No. 2, R1103–R1106 (1997).
6. M. Sheik-Bahae, A. A. Said, E. W. Van Stryland, Opt. Lett., 14, 955–957 (1989).
7. M. Sheik-Bahae, A. Said, T. Wei, D. Hagan, E. W. Van, IEEE J. Quantum. Electron., 26, No. 4, 760–769 (1990).
8. R. Ganeev, I. Kulagin, A. Ryasnyanskii, R. Tugushev, T. Usmanov, Opt. Spectrosc., 94, No. 4, 561–568 (2003).
9. S. Gómez, F. Cuppo, A. Neto Figueiredo, Braz. J. Phys., 33, No. 4, 813–820 (2003).
10. Z. Biyiklioglu, T. Arslan, F. Alawainati, H. Manaa, A. Jaffar, F. Z. Henari, Inorg. Chim. Acta, 486, 345–351 (2019).
11. R. Kumar, S. Rao, L. Giribabu, D. Rao, Chem. Phys. Lett., 447, No. 4-6, 274–278 (2007).
12. Z. Li, F. Gao, Z. Xiao, G. Ao, X. Wu, Y. Fang, Z. Nie, T. Wei, J. Yang, Y. Wang, X. Zhang, J. Zuo, Y. Song, Dyes Pigments, 119, 70–74 (2015).
13. H. L. Saadon, Opt. Quantum. Electron., 48, 40–46 (2016), https://doi.org/10.1007/s11082-015-0336-6
14. S. Mathews, S. Chaitanya Kumar, L. Giribabu, S. Venugopal Rao, Opt. Commun., 280, No. 1, 206–212 (2007).
15. S. Mathews, S. Kumar, L. Giribabu, S. Rao, Mater. Lett., 61, No. 22, 4426–4431 (2007).
16. H. Manaa, A. Mulla, S. Makhseed, M. Al-Sawah, J. Samuel, Opt. Mater., 32, No. 1, 108–114 (2009).
17. H. Manaa, A. Tuhl, J. Samuel, A. Al-Mulla, N. Al-Awadi, S. Makhseed, Opt. Commun., 284, No. 1, 450–454 (2011).
18. M. Rashidian, D. Dorranian, Rev. Adv. Mater. Sci., 40, 110–126 (2015).
19. A. Almosawe, H. L. Saadon, Chin. Opt. Lett., 11, 041902–041905 (2013).
20. P. Zhao, Z. Wang, J. Chen, Y. Zhou, F. Zhang, Opt. Mater., 66, 98–105 (2017).
Review
For citations:
Alawainati F., Manaa H., Henari F., Biyiklioglu Z., Arslan T., Jaafar A. Nonlinear Optical Properties of Novel Metallophthalocyanine. Zhurnal Prikladnoii Spektroskopii. 2021;88(5):717-723.
Views: 197
Email this article 