Multivariate Calibration of Concentrations of C, Mn, Si, Cr, Ni, and Cu in Low-Alloyed Steels from Raw Spectra with Low Resolution Obtained by Laser-Induced Breakdown Spectroscopy Method
Abstract
Multivariate models were developed on the base of raw low-resolution LIBS spectra of reference samples of low-alloyed steels for calibration of the concentrations of six chemical elements (C, Mn, Si, Cr, Ni, and Cu), which are the main technological and alloying additives. The multivariate models for C (RMSE=0.06% for test dataset) and Mn (0.12%) content are quantitative with an accuracy sufficient for practical application, semi-quantitative for Si (0.09%) and Ni (0.07%), and qualitative for Cr (0.13%) and Cu (0.08%).
About the Authors
M. V. BelkovBelarus
Minsk
D. A. Borisevich
Belarus
Minsk
K. Y. Catsalap
Belarus
Minsk
M. A. Khodasevich
Belarus
Minsk
References
1. Y. Wei, R. S. Varanasi, T. Schwarz, L. Gomell, H. Zhao, D. J. Larson, B. Sun, G. Liu, H. Chen, D. Raabe, B. Gault. Patterns, 2, N 2 (2021) 1-14
2. S. Grünberger, S. Eschlböck-Fuchs, J. Hofstadler, A. Pissenberger, H. Duchaczek, S. Trautner, J. D. Pedarnig. Spectrochim. Acta B: At. Spectrosc., 169 (2020) 1-11
3. M. W. Vaughan, P. Samimi, S. L. Gibbons, R. A. Abrahams, R. C. Harris, R. E. Barber, I. Karaman. Scr. Mater., 184 (2020) 63-69
4. Ch. J. Rao, S. Ningshen, J. Philip. Spectrochim. Acta B: At. Spectrosc., 172 (2020) 1-10
5. D. Syvilay, J. Guezenoc, B. Bousquet. Spectrochim. Acta B: At. Spectrosc., 161 (2019) 1-34
6. F. B. Gonzaga, C. Pasquini. Spectrochim. Acta: At. Spectrosc., 69 (2012) 20-24
7. H. Kim, Sang-Ho Na, Song-Hee Han, S. Jung, Y. Lee. Opt. Laser Technol., 112 (2019) 117-125
8. M. Cui, Y. Deguchi, Ch. Yao, Zh. Wang, S. Tanaka, D. Zhang. Spectrochim. Acta B: At. Spectrosc., 167 (2020) 1-7
9. V. Motto-Ros, D. Syvilay, L. Bassel, E. Negre, F. Trichard, F. Pelascini, J. El Haddad, A. Harhira, S. Moncayo, J. Picard, D. Devismes, B. Bousquet. Spectrochim. Acta B: At. Spectrosc., 140 (2018) 54-64
10. T. A. Labutin, A. M. Popova, S. M. Zaytsev, N. B. Zorova, M. V. Belkov, V. V. Kiris, S. N. Raikov. Spectrochim. Acta B, 99 (2014) 94-100
11. S. Wold, M. Sjöström, L. Eriksson. Chemom. Intell. Lab. Systems, 58, N 2 (2001) 109-130
12. M. D. Peris-Díaz, A. Krężel. TrAC Trends Analytiс. Chem., 135 (2021) 1-21
13. ASTM Standard Practices for Infrared Multivariate Quantitative Analysis, Designation: E1655-05 (2012) 1-29
14. S. Nawar, A. M. Mouazen. Computers and Electronics in Agriculture, 151 (2018) 469-477
15. K. H. Esbensen, P. Geladi, A. Larsen. NIR News, 25, N 5 (2014) 24-28
16. E. V. dos Santos Pereira, D. D. de Sousa Fernandes, M. C. de Araújoc, P. H. Diniz, M. I. Maciela. LWT – Food Sci. and Technology, 127 (2020) 1-10
Review
For citations:
Belkov M.V., Borisevich D.A., Catsalap K.Y., Khodasevich M.A. Multivariate Calibration of Concentrations of C, Mn, Si, Cr, Ni, and Cu in Low-Alloyed Steels from Raw Spectra with Low Resolution Obtained by Laser-Induced Breakdown Spectroscopy Method. Zhurnal Prikladnoii Spektroskopii. 2021;88(5):737-742. (In Russ.)