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Plasmonic Structures Based on Hydroxyapatite/Silver Nanocomposite for Surface-Enhanced Raman Spectroscopy
Abstract
Using glucose as a reducing agent, a hydroxyapatite-silver (HA)Ag nanocomposite is synthesized, in which one silver nanoparticle is bound to each HA particle. The structural and optical properties of the nanocomposite are investigated. The technique of formation of plasmonic films (HA)Ag on the glass substrates surface is optimized. The role of modification of a glass surface with polyethyleneimine in the formation of homogeneous plasmonic coatings is demonstrated. The surface-enhanced Raman spectra (SERS) of the cationic porphyrin CuTMpyP4 adsorbed on the surface of the (HA)Ag film are measured. The detection limit of CuTMpyP4 is established as 10-12 M, which is comparable to the sensitivity of the wellknown solid-state SERS-active substrate.
About the Authors
A. Yu. Panarin
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
A. V. Abakshonok
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
P. Mojzes
Institute of Physics at Charles University
Czech Republic
Czech Republic
Prague
S. N. Terekhov
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
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Review
For citations:
Panarin A.Yu., Abakshonok A.V., Mojzes P., Terekhov S.N. Plasmonic Structures Based on Hydroxyapatite/Silver Nanocomposite for Surface-Enhanced Raman Spectroscopy. Zhurnal Prikladnoii Spektroskopii. 2021;88(5):748-754. (In Russ.)
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