Preview

Zhurnal Prikladnoii Spektroskopii

Advanced search

ROTATIONAL ISOMERS, INTRAMOLECULAR HYDROGEN BOND, AND IR SPECTRA OF o-VINYLPHENOL HOMOLOGUES

Abstract

The n(ОН) stretching mode bands in IR spectra of the solutions of five o-vinylphenol homologues (o-VPh) in CCl4 and n-hexane low polarity solvents were studied. Several rotamers with a free OH group were found in the solution of o-VPh and its methyl substituted in n-hexane. According to the calculations by the B3LYP/cc-pVTZ method, the proportion of rotamers in o-VPh homologues with intramolecular hydrogen bond О-Н…p (IHB) varies from 22 to 97% in the gas and in the cyclohexane medium. Theoretical values of the effective enthalpy -ΔН of its IHB vary in the range 0.20-2.24 kcal/mol.

For citations:


Glazunov V.P., Berdyshev D.V., Balaneva N.N., Radchenko O.S., Novikov V.L. ROTATIONAL ISOMERS, INTRAMOLECULAR HYDROGEN BOND, AND IR SPECTRA OF o-VINYLPHENOL HOMOLOGUES. Zhurnal Prikladnoii Spektroskopii. 2018;85(1):14-26. (In Russ.)

Views: 303


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0514-7506 (Print)