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STOICHIOMETRY OF SILICON DIOXIDE FILMS OBTAINED BY ION-BEAM SPUTTERING

Abstract

We used infrared spectrometry to study the composition of SiOx films obtained by the method of ion-beam sputtering (IBS) of silicon and quartz targets. Films of 150-390 nm were formed on silicon substrates. It was found that an increase in the partial pressure of oxygen in the working gas, an increase in the temperature of the substrate, and the presence of a positive potential on the target during the reactive IBS of silicon led to a shift in the main absorption band of νas to the high-frequency region and an increase in the composite index from 1.41 to 1.85. During the IBS of a quartz target the stoichiometry of the films deteriorates with the increase of the energy of the sputtering argon ions. It can be due to increasing the deposition rate. An increase in the current of the thermionic compensator, an increase in the substrate temperature, and the addition of oxygen contributed to the formation of SiOx films with improved stoichiometry.

About the Authors

E. V. Telesh
Belarusian State University of Informatics and Radioelectronics
Russian Federation


A. P. Dostanko
Belarusian State University of Informatics and Radioelectronics
Russian Federation


O. V. Gurevich
Belarusian State University of Informatics and Radioelectronics
Russian Federation


References

1. Н. А. Валишева, А. А. Гузев, А. П. Ковчавцев, Г. Л. Курышев, Т. А. Левцова, 3. В. Панова. Микроэлектроника, 38, № 2 (2009) 99-106

2. S.-I. Jun, T. E. McKnight, A. V. Melechko, M. L. Simpson, P. D. Rack. Electr. Lett., 41, N 14 (2005) 822-823

3. H. Faraby, M. Dibattista, P. R. Bandaru. J. Appl. Phys., 116, N 20, 204301 (2014)

4. A. Strass, P. Bieringer, W. Hansch, V. Fuenzalida, A. Alvarez, J. Luna, I. Martil, F.L. Martinez, I. Eisele. Thin Solid Films, 349 (1999) 135-146

5. S. A. Khodier, H. M. Sidki. J. Mater. Sci.: Mater. Electron., 12, N 2 (2001) 107-109

6. H. Qi, M. Zhu, M. Fang, S. Shao, C. Wie, K. Yi, J. Shao. High Power Laser Sci. Eng., 1, N 1 (2013) 36-43

7. L. Galais, H. Krol, J. Y. Natoli, M. Commandre, M. Cathelinaud, L. Roussel, M. Leguime, C. Amra. Thin Solid Films, 515 (2007) 3830-3836

8. C. Wei, K. Yi, Z. Fan, J. Shao. Appl. Opt., 51, N 28 (2012) 6781-6788

9. D. I. Kushner, M. A. Hickner. Langmuir, 33, N 21 (2017) 5261-5268

10. H.-D. Kurland, J. Grabow, C. Stötzel, F. A. Müller. J. Ceram. Sci. Tech., 5, N 4 (2014) 275-280

11. V. Bhatt, S. Chandra, S. Kumar, C. M. S. Reuthan, P. N. Dixit. Indian J. Pure & Appl. Phys., 45 (2007) 377-381

12. W.-F. Wu, B.-S. Chio. Semicond. Sci. Technol., 11 (1996) 1317-1321

13. I. Radovič, Y. Serruys, Y. Limoge, M. Milosavlevič, N. Romčevič, N. Bibič. Optoelectron. Adv. Mater., Rapid Commun., 1, N 5 (2007) 247-251

14. Е. В. Телеш, Н. К. Касинский, В. С. Томаль. Вестн. ПГУ, № 4 (2012) 121-127

15. P. Rüffer, A. Heft, R. Linke, T. Struppert, B. Grünler. Surface and Coatings Technol., 232 (2013) 582-586

16. J.-K. Kim, S.-H. Jeong, B.-S. Kim, S.-H. Shim. J. Phys. D: Appl. Phys., 37 (2004) 2425-2441

17. Ю. А. Пентин, Л. В. Вилков. Физические методы исследования в химии, Москва, Мир (2006) 199-214

18. W. A. Pliskin. J. Vac. Sci. Technol., 14, N 5 (1977) 1064-1081

19. M. Misawa, Y. Kobayashi, K. Suzuki. Proc. Int. Ion Engineering Congress, ISIAT'83 & IPAT’83, Kyoto (1983) 957-962

20. D. S. Veselov, Yu. A. Voronov. J. Phys.: Conf. Ser., 747 (2016) 012022

21. G. Emiliani, S. Scaglione. J. Vac. Sci. Technol., A5, N 4 (1987) 1824-1827

22. А. П. Достанко, Е. С. Акулич, В. Я. Ширипов, С. А. Соболев. Журн. прикл. спектр., 50, № 3 (1989) 436-439 [A. P. Dostanko, E. S. Akulich, V. Ya. Shiripov, S. A. Sobolev. J. Appl. Spectr., 50 (1989)]

23. A. L. Shabalov, M. S. Feldman. Thin Solid Films, 110, N 3 (1983) 215-224

24. I. W. Boyd, J. B. Wilson. J. Appl. Phys., 53, N 6 (1982) 4166-4172

25. А. П. Достанко, С. М. Аваков, Л. П. Ануфриев, С. В. Бордусов, Д. А. Голосов, С. М. Завадский, Н. С. Ковальчук, А. О. Коробко, В. Л. Ланин, С. И. Мадвейко, В. А. Русецкий, Е. В. Телеш, Е. А. Титко, Г. А. Трапашко. Интегрированные технологии микро- и наноструктурированных слоев: монография, Минск, Бестпринт (2013) 157-161

26. J. P. Nair, I. Zon, M. Oron, R. Popovitz-Biro, Y. Feldman, I. Lubomirsky. J. Appl. Phys., 92, (2002) 4784-4790


Review

For citations:


Telesh E.V., Dostanko A.P., Gurevich O.V. STOICHIOMETRY OF SILICON DIOXIDE FILMS OBTAINED BY ION-BEAM SPUTTERING. Zhurnal Prikladnoii Spektroskopii. 2018;85(1):76-81. (In Russ.)

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